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There are many types of signaling molecules, however, including cAMP, nitric oxide, estrogen, norepinephrine, and even reactive oxygen species (ROS)

The effect of omega-3 fatty acids supplementation on inflammatory biomarkers in subjects with migraine: a randomized, double-blind, placebo-controlled trial

[1] You can reduce the appearance of this dark pigmentation by using a topical over-the-counter skin treatment, a topical prescription skin lightening cream, tranexamic acid, chemical peels, or lasers

It is also worth noting that two of the supporting studies [38, 64] were rated as having a moderate risk of bias, which may influence the reliability of their findings