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Recognizing the issue of microplastic accumulation in bioplastic degradation research, the study focuses on enhancing substrate degradability using a simple and economically viable pretreatment (TA 30 C), achieving a maximum CA degradation of 91% with optimal removal of acetyl groups (C = O band at 1,750 1,800 cm 1 , C-H bending vibration at 1,350 1,450 cm 1 , and CO stretch at 1,270 1,210 cm 1 ) of CA